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Time-resolved mass spectrometry : ウィキペディア英語版 | Time-resolved mass spectrometry
Time-resolved mass spectrometry (TRMS) is a strategy in analytical chemistry that uses mass spectrometry platform to collect data with temporal resolution. Implementation of TRMS builds on the ability of mass spectrometers to process ions within sub-second duty cycles. It often requires the use of customized experimental setups. However, they can normally incorporate commercial mass spectrometers. As a concept in analytical chemistry TRMS encompasses instrumental developments (e.g. interfaces, ion sources, mass analyzers), methodological developments, and applications. == Applications ==
An early application of TRMS was in the observation of flash photolysis process.〔(【引用サイトリンク】url=http://scitation.aip.org/content/aip/journal/jcp/46/3/10.1063/1.1840834 )〕 It took advantage of a time-of-flight mass analyzer.〔(【引用サイトリンク】url=http://iopscience.iop.org/0950-7671/44/6/303 )〕 TRMS currently finds applications in the monitoring of organic reactions, formation of reactive intemediates, enzyme-catalyzed reactions, convection, protein folding, extraction, and other chemical and physical processes.
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